JEE Main 2019 Chemistry question

ChemistryElectrochemistryJEE Main 2019

For the cell Zn(s)|Zn(aq)||M(aq)|M(s), different half cells and their standard electrode potentials are given below:

| M(aq)/M(s) | Au(aq)/Au(s) | Ag(aq)/Ag(s) | Fe(aq)/Fe(aq) | Fe(aq)/Fe(s) | |---|---|---|---|---| | (V) | 1.40 | 0.80 | 0.77 | −0.44 |

If = −0.76 V, which cathode will give maximum value of per electron transferred?

Answer: (A)

Solution

/n: Au 2.16/3 = 0.72, Ag 1.56/1, Fe/Fe 1.53/1, Fe 0.32/2 — maximum for Ag.

Question ID VK-010507