JEE Main 2024 Chemistry question

ChemistryRedox ReactionsJEE Main 2024

Given below are two statements: one is labeled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): In aqueous solutions Cr is reducing while Mn is oxidising in nature. Reason (R): Extra stability to half filled electronic configuration is observed than incompletely filled electronic configuration. In the light of the above statements, choose the most appropriate answer from the options given below:

Answer: (A)

Solution

Cr²⁺ (d⁴) → Cr³⁺ (d³, stable t₂g³) and Mn³⁺ (d⁴) → Mn²⁺ (d⁵, half filled), so

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Question ID VK-011161