JEE Main 2024 Chemistry question

ChemistryChemical Bonding and Molecular StructureJEE Main 2024

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): NH and NF molecule have pyramidal shape with a lone pair of electrons on nitrogen atom. The resultant dipole moment of NH is greater than that of NF. Reason (R): In NH, the orbital dipole due to lone pair is in the same direction as the resultant dipole moment of the N–H bonds. F is the most electronegative element. In the light of the above statements, choose the correct answer from the options given below:

Answer: (A)

Solution

In NH₃ the lone-pair moment and the bond moments add (1.47 D); in NF₃ the N–F bond moments oppose the lone-pair moment (0.24 D).

Question ID VK-011612