JEE Main 2026 Chemistry question

ChemistryAminesJEE Main 2026

The number of compounds from the following which can undergo reaction with Br₂/KOH (alcoholic) to give respective products and these respective products can also be obtained separately by Gabriel phthalimide reaction is: benzamide (C₆H₅CONH₂); phenylacetamide (C₆H₅CH₂CONH₂); acetamide (CH₃CONH₂); N-ethylcyclohexanecarboxamide (C₆H₁₁CONHCH₂CH₃); N-methylpivalamide ((CH₃)₃CCONHCH₃); cyclohexanecarboxamide (C₆H₁₁CONH₂).

Answer: (C)

Solution

Br₂/KOH (Hofmann bromamide degradation) works only on primary amides RCONH₂, ruling out the two N-substituted amides. Benzamide would give aniline, an aromatic amine that Gabriel synthesis cannot

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Question ID VK-015627