JEE Main 2024 Chemistry question
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : There is a considerable increase in covalent radius from N to P. However from As to Bi only a small increase in covalent radius is observed. Reason (R) : Covalent and ionic radii in a particular oxidation state increases down the group. In the light of the above statements, choose the most appropriate answer from the options given below :
Solution
The covalent radius increases considerably from N to P, but from As to Bi the increase is very small, because the presence of d and f orbital electrons increases the effective nuclear charge.
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