MHT CET Chemistry question

ChemistryAldehydes, Ketones and Carboxylic AcidsMHT CET

Consider the acidity of the carboxylic acids

i.

ii.

iii.

iv.

Which of the following order is CORRECT?

Answer: (D)

Solution

A nitro group (-I, -M) increases the acidity of benzoic acid; the ortho isomer is strongest (pKa 2.17, ortho effect), then the para (3.44) and meta (3.45) isomers,

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Question ID VK-080938