MHT CET 2023 Chemistry question

ChemistryHaloalkanes and HaloarenesMHT CET 2023

Identify substrate 'A' in the following sequence of reaction

A B 2-Methylbutane

Answer: (B)

Solution

Work backwards. Na/ether with is the Wurtz reaction: \mathrm{R{-}Cl + 2Na + Cl{-}C_2H_5 \to R{-}C_2H_5 + 2NaCl}. The product 2-methylbutane is \mathrm{(CH_3)_2CH{-}CH_2CH_3}, i.e. isopropyl + ethyl. So B must be the isopropyl halide, 2-chloropropane . B is obtained from

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Question ID VK-098012