MHT CET 2026 Chemistry question

ChemistryAminesMHT CET 2026

Aniline on treatment with / HCl at about gives a compound A, which on further treatment with CuCN / KCN gives a compound B, which when reacts with / Ni gives a compound C. The compound C on reaction with HNO2 gives a compound D. The structure of D is:

Answer: (A)

Solution

Step 1: aniline + /HCl at 0-5 C gives benzenediazonium chloride, (A). Step 2: CuCN/KCN (Sandmeyer reaction) gives benzonitrile, (B). Step 3: /Ni reduces the nitrile to benzylamine, (C).

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Question ID VK-101499