Identify the product 'B' in the following sequence of reactions.
Ethanenitrile A B +
(A)Ethylamine
(B)Ethanamide
(C)Ethanol
(D)EthanalCorrect
Answer: (D)
Solution
This is Stephen's reduction. Ethanenitrile () is partially reduced by stannous chloride and HCl to the imine hydrochloride, \mathrm{CH_3CH{=}NH{\cdot}HCl} (A), which on acid hydrolysis gives the aldehyde and ammonium chloride: Missing close brace\mathrm{CH_3CHH_2O\xrightarrow{H_3O^+}$
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