JEE Advanced 2026 Chemistry question

ChemistrySolutionsJEE Advanced 2026

In a solvent S, a compound B is partially dissociated into C and D as given below:

B 2C+2D

B, C and D are non-volatile in nature. The molar mass of B is times the molar mass of S. The standard boiling point and the standard enthalpy of vaporization of S are and , respectively ( is the gas constant in ). A solution of B in S with an initial concentration of B as (mass/mass) has a boiling point of at bar pressure. In this solution, the mole percent of B that has been dissociated is .

Answer: 33.17

Solution

**Step 1 — ebullioscopic constant of S.** Let be the molar mass of S in . With K and ,

===16M\ K kg mol^{-1}.

**Step 2 — molality.** The molar mass

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Question ID VK-104800