JEE Main 2017 Chemistry question

ChemistryPrinciples Related to Practical ChemistryJEE Main 2017

A solution containing a period-IV cation gives a precipitate on passing . A solution of this precipitate in dil. HCl produces a white precipitate with NaOH solution and bluish-white precipitate with basic potassium ferrocyanide. The cation is:

Answer: (2)

Solution

Follow the colours, which are the decisive clue. **Sulphide:** all four cations give sulphides, but only is **white**; MnS is buff/flesh-coloured, while NiS and CoS are black. **With NaOH:** the solution gives a **white** precipitate, which is — is white but

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Question ID VK-115816