Which sequence of reactions shows correct chemical relation between sodium and its compounds? [DCE 2009]
(A); \quad Na_2O \xrightarrow{CO_2} Na_2CO_3 \xrightarrow{\Delta} Na
(B)Na \xrightarrow{O_2} Na_2O \xrightarrow{H_2O} NaOH \xrightarrow{CO_2} Na_2CO_3 \xrightarrow{\Delta} Na
(C); \quad Na + H_2O \to NaOH \xrightarrow{CO_2} Na_2CO_3 \xrightarrow{\Delta} Na
(D)Na_2CO_3 \xrightarrow{HCl} NaCl \xrightarrow{Electrolysis (molten)} Na + Cl_2Correct
Answer: (D)
Solution
Sequences (A), (B) and (C) all include the step "", but sodium carbonate is thermally very stable and does not decompose to give metallic sodium on heating, so these chains are chemically invalid. The only genuinely valid, industrially real
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