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JEE Main Chemistry question

ChemistryHaloalkanes and HaloarenesJEE Main

The SN1 reactivity of the following halides, (i) (CH₃)₃CBr, (ii) a secondary benzylic bromide, (iii) (C₆H₅)₂C(CH₃)Br, (iv) a primary benzylic bromide, (v) C₂H₅Br, will be in the order

Answer: (D)

Solution

The doubly-benzylic, tertiary cation from (iii) [(C₆H₅)₂C(CH₃)⁺] is by far the most resonance- and

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Question ID VK-139323