JEE Main Chemistry question

ChemistryAminesJEE Main

Which substance will not react with ( = Phenyl) to give dye? A ring with CH3 and OH (activated, p-cresol-type); a dichloro-substituted phenol; a nitro-substituted phenol; a trimethylphenol (both ortho/para positions blocked by methyl groups)

Answer: (D)

Solution

Azo coupling with a diazonium salt requires an open, activated ring position (usually para, or ortho if para is blocked) on the phenol for electrophilic attack; if all ortho and para positions relative to

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Question ID VK-148625