JEE Main Chemistry question

ChemistryOrganic Chemistry - Some Basic Principles and TechniquesJEE Main

Statement 1: R–C≡O⁺ is more stable than R–C⁺=O. Statement 2: Resonance in the carbonyl compound provides C⁺ and O⁻.

Answer: (B)

Solution

Statement 1 is true: the acylium-type cation with a full C≡O triple bond and formal positive charge on the terminal, electronegative oxygen is a poor resonance structure, whereas a resonance structure bearing the positive charge on carbon with the full double bond to oxygen retained in a different sense is actually

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Question ID VK-149401