JEE Main Chemistry question
Acetaldehyde reacts with PCl₅ to give:
Answer: (C)
Solution
PCl₅ converts the aldehyde's C=O into a gem-dichloride: CH₃CHO + PCl₅ → CH₃CHCl₂ (ethylidene dichloride, 1,1-dichloroethane) + POCl₃.
Acetaldehyde reacts with PCl₅ to give:
PCl₅ converts the aldehyde's C=O into a gem-dichloride: CH₃CHO + PCl₅ → CH₃CHCl₂ (ethylidene dichloride, 1,1-dichloroethane) + POCl₃.