JEE Main Chemistry question

Aniline is not the major product in one of the following reactions. Identify that reaction. [EAMCET 2003]

(A)
(B)Correct
(C)
(D)

Answer: (B)

Solution

Reactions (a) (Bucherer-type amination of phenol), (c) (ammonolysis of chlorobenzene under pressure/catalyst) and (d) (Fe/HCl reduction of nitrobenzene) all give aniline as the major product. Reaction (b), zinc dust with

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Question ID VK-150257