JEE Main Chemistry question
**Matrix Match.** Match the reactions in Column-I with the name reactions in Column-II.
| Column-I | Column-II | |---|---| | (A) (CH_3)_3C-OH + HCN \xrightarrow{H^{+}} (CH_3)_3C-NH_2 | (1) Grignard | | (B) CH_3CONH_2 + Br_2 + KOH \rightarrow RNH_2 | (2) Mendius | | (C) CH_3CN + 4H \xrightarrow[alc.]{Na} CH_3CH_2NH_2 | (3) Hofmann bromamide | | (D) CH_3MgBr + ClNH_2 \rightarrow CH_3NH_2 | (4) Ritter |
Answer: (A)
Solution
(A) Acid-catalyzed addition of a tertiary alcohol/carbocation to followed by hydrolysis is the Ritter reaction (A-4). (B) Degradation of an amide with is the Hofmann bromamide reaction (B-3). (C)
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