JEE Main Chemistry question

ChemistryAminesJEE Main

, and give as the product. The intermediates of the reaction are

(A) (B) (C) (D) .

The correct answer is

Answer: (A)

Solution

In the Hofmann bromamide degradation, acetamide is first -brominated to (A). Base-mediated loss of gives a nitrene, which rearranges (with migration of the methyl group

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Question ID VK-150417