JEE Main Chemistry question

ChemistryPolymersJEE Main

Not in JEE Main or NEET syllabus

Arrange the following monomers in order of decreasing ability to undergo cationic polymerisation.

I. II. III.

Answer: (B)

Solution

Cationic polymerization proceeds through a benzylic carbocation on the vinyl-substituted benzene ring, which is stabilized by electron-releasing ring substituents and destabilized by electron-withdrawing ones. The methoxy group (–OCH, monomer III) is the strongest electron donor by resonance,

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Question ID VK-151458