JEE Advanced Chemistry question

ChemistryAminesJEE Advanced

Match the compounds given in List-I with their characteristic reactions given in List-II. Select the correct option. Column-I (A) (B) (C) (D) CH_3CH(OH)CH_3 Column-II (p) Alkaline hydrolysis (q) With (alcohol) and produces bad smell (r) Gives white ppt. with ammoniacal (s) With Lucas reagent cloudiness appears after 5 minutes

Answer: (C)

Solution

(A) (n-butylamine, a primary amine) undergoes the carbylamine reaction with (alcoholic)/, producing the foul-smelling isocyanide — matches (q = ii). (B) (propyne, a terminal alkyne) gives a white precipitate of its silver acetylide with ammoniacal — matches (r

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Question ID VK-159262