JEE Advanced Chemistry question

ChemistryThe p-Block ElementsJEE Advanced

Match the compounds (Column-I) with their structures (Column-II).

Column-I: (A) XeF4 (B) XeF6 (C) XeO3 (D) XeO4 Column-II: (p) Distorted octahedral (q) Tetrahedral (r) Square planar (s) Pyramidal

Codes:

Answer: (A)

Solution

XeF4 (AX4E2, sp3d2) is square planar (r). XeF6 (AX6E1, sp3d3) has a lone pair that distorts the ideal octahedron, so it is best described as "distorted octahedral" (p).

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Question ID VK-159519